Mitkem Corporation - Analytical Guide

Analytical Guide
Table 1 | Table 2 | Table 3

Table 2
Recommended Container, Preservation Techniques and Holding Times For CLP/ASP Analyses

Analytes	Method	Containers	Required* Volume	Preservation	Holding Times
Volatile Organics
Solid	CLP/ASP	Amber glass jar with Teflon lining	Minimal head- space in jar	4°C	10 days from VTSR
Aqueous	CLP/ASP	40mL VOA vials with Teflon septum	40mL	4°C HCl, pH<2	10 days from VTSR
Aqueous	CLP Low	40mL VOA vials with Teflon septum	40mL	4°C HCl, pH<2	10 days from VTSR
Semivolatile Organics
Solid	CLP/ASP	Amber glass jar with Teflon lining	30gram	4°C	10 days from VTSR Analysis within 40 days
Aqueous	CLP/ASP	Amber glass bottle with Teflon lining	1L	4°C	5 days from VTSR Analysis within 40 days
Aqueous	CLP Low	Amber glass bottle with Teflon lining	1L	4°C	5 days from VTSR Analysis within 40 days
Organochlorine Pesticide/PCB
Solid	CLP/ASP	Amber glass jar with Teflon lining	30gram	4°C	10 days from VTSR Analysis with 40 days
Aqueous	CLP/ASP	Amber glass bottle with Teflon lining	1L	4°C	5 days from VTSR Analysis within 40 days
Aqueous	CLP Low	Amber glass bottle with Teflon lining	1L	4°C	5 days from VTSR Analysis within 40 days
Cyanide
Solid	CLP/ASP	Amber glass jar	2gram	4°C	12 days from VTSR
Aqueous	CLP/ASP	Polyethylene bottle	50mL	4°C NaOH, pH>12	12 days from VTSR
Total Metals except Mercury
Solid	CLP/ASP	Amber glass jar	2gram	4°C	180 days from VTSR
Aqueous	CLP/ASP	Polyethylene bottle	100mL	HNO₃, pH<2	180 days from VTSR
Mercury
Solid	CLP/ASP	Amber glass jar	10gram	4°C	26 days from VTSR
Aqueous	CLP/ASP	Polyethylene bottle	100mL	4°C HNO₃, pH<2	26 days from VTSR

* These represent minimum required volume. Additional sample volumes should be collected to minimize headspace loss for volatile analysis. Additional sample aliquot are also required to perform QA/QC functions (e.g. spikes, duplicates), % moisture for solid samples and sample re-analysis (if needed).

^a For Massachusetts analyses, the volatile soil samples are to be preserved in methanol in the field.

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Last updated: January 14, 2008